.
pg 73
polyene
Polyenes are poly-unsaturated organic compounds that contain at least three alternating double and single carbon–carbon bonds. These carbon–carbon double bonds interact in a process known as conjugation.
https://en.m.wikipedia.org/wiki/Retinal
2 methyl groups joined to one carbon or 1 ethyl group is more electron donating by induction?
https://en.m.wikipedia.org/wiki/1,4-Benzoquinone
benzoquinone can have resonance?
cks say so
Originally posted by Flying grenade:2 methyl groups joined to one carbon or 1 ethyl group is more electron donating by induction?
Originally posted by Flying grenade:https://en.m.wikipedia.org/wiki/1,4-Benzoquinone
benzoquinone can have resonance?
cks say so
cks say trans form more than cis
https://www.dropbox.com/s/ij42vz0qidnr17e/20161006_122453.jpg?dl=0
i still love ur previous post
https://www.dropbox.com/s/fspcryinswek27q/20161006_122808.jpg?dl=0
https://www.dropbox.com/s/mcg0k777iuz11rf/20161006_122757.jpg?dl=0
cks wrote slow in All his sn2 mechanism
https://www.dropbox.com/s/chan9dxxawjj1cu/20161006_123319-1.jpg?dl=0
https://www.dropbox.com/s/nu04p9d3tkvhbox/20161006_125259.jpg?dl=0 pg 194
what product will form when ester, amides, acyl halides react with 24dnph, Nu Sub to give what?
why is OH- hydroxyl group a better leaving group than carbanion R- or hydride H- ?
OH- is also a strong nucleophile like R- and H- right ?
cks say due to the above reason, aldehydes and ketone undergoes nu add, carboxylic acid undergo nu sub
https://www.dropbox.com/s/hld2siryk5xcyxt/20161006_135648.jpg?dl=0
how do we know which substituent group is dominant?
and in this case cks writes weakly activating CH3 groups dominate the strongly deactivating NO2 group ?
e- from NO2 group can delocalise into b.ring of nitrobenzene too right?
https://www.dropbox.com/s/akatwjm0cr5ytdx/20161006_144236.jpg?dl=0
he writes NaBH4 can be put in aqueous soln
https://www.dropbox.com/s/oogvzztova57mf1/20161006_152832.jpg?dl=0
2 methyl groups joined to one carbon or 1 ethyl group is more electron donating by induction?
should be 2 methyl groups.
what about 2 ethyl groups compared to 3 methyl groups?
Originally posted by Flying grenade:https://www.dropbox.com/s/nu04p9d3tkvhbox/20161006_125259.jpg?dl=0 pg 194
what product will form when ester, amides, acyl halides react with 24dnph, Nu Sub to give what?
Originally posted by Flying grenade:why is OH- hydroxyl group a better leaving group than carbanion R- or hydride H- ?
OH- is also a strong nucleophile like R- and H- right ?
cks say due to the above reason, aldehydes and ketone undergoes nu add, carboxylic acid undergo nu sub
Originally posted by Flying grenade:https://www.dropbox.com/s/hld2siryk5xcyxt/20161006_135648.jpg?dl=0
how do we know which substituent group is dominant?
and in this case cks writes weakly activating CH3 groups dominate the strongly deactivating NO2 group ?
Originally posted by Flying grenade:e- from NO2 group can delocalise into b.ring of nitrobenzene too right?
https://www.dropbox.com/s/akatwjm0cr5ytdx/20161006_144236.jpg?dl=0
Originally posted by Flying grenade:2 methyl groups joined to one carbon or 1 ethyl group is more electron donating by induction?
should be 2 methyl groups.
what about 2 ethyl groups compared to 3 methyl groups?
Originally posted by UltimaOnline:
Who lagi strong? Who lagi unstable?
why R- and H- more strong and unstable than OH- ?
Originally posted by UltimaOnline:
He's right.
y
Originally posted by UltimaOnline:
Irrelevant, because in such scenarios other factors (figure them out yourself, go ask your school teacher or private tutor, and don't reveal them on the forum, edart sterces) will outweigh inductive effects.
HAHAHAHA OK I GOT IT ALR